The only way to solve this problem is to draw it out. Work with your lines and imagination. Think angles and triangles, specifically a right triangle (90 degree triangle).
From the center of the circle, draw two lines - one joining a vertex of the triangle, and the other line joining the center of the circle and the midpoint of the side of the triangle next to the vertex.
If a is the side of the triangle, r is the radius of the circle, and hopefully if you are familiar with trignometry, can you see that
tan(60/2)=r/(a/2)=Opposite side/Adjacent side
Note that tan 30 degrees=1/sqrt(3). Thus, you can find 'a', which is twice of 'a/2'.
Thus 1/sqrt(3)=2r/a =>a=2*sqrt(3)*r or r=a/(2*sqrt(3)). Thus, if you know 'r', you can solve for 'a' or vice versa.
Cheers,
Sai.